106930-36-3Relevant academic research and scientific papers
A route to artificial glycoconjugates and oligosaccharides via enzymatically resolved glycals: Dramatic effects of the handedness of the sugar domain upon the properties of an anthracycline drug
Berkowitz, David B.,Danishefsky, Samuel J.,Schulte, Gayle K.
, p. 4518 - 4529 (2007/10/02)
Racemic, fully synthetic glycals of considerable structural variety may be kinetically resolved via enzymatically mediated transesterification using Lipase PS-30 from Pseudomonas cepacia as catalyst and vinyl acetate as acyl donor. This methodology provid
Enzymatic resolution of racemic glycals: An application of the wong acylation method
Berkowitz,Danishefsky
, p. 5497 - 5500 (2007/10/02)
Kinetic resolution of racemic, fully synthetic, artificial glycals bearing a free hydroxyl group at C3 was accomplished through the more rapid acylation of the 'D'-antipode with vinyl acetate as acyl donor and Lipase PS-30 from Pseudomonas cepa
A Concise and Stereoselective Route to the Predominant Stereochemical Pattern of the Tetrahydropyranoid Antibiotics: An Application to Indanomycin
Danishefsky, Samuel J.,DeNinno, Shari,Lartey, Paul
, p. 2082 - 2089 (2007/10/02)
The reactions of (E)- and (Z)-crotylsilanes of the type R3Si-CH2-CH=CH-CH3 with activated glycal derivatives in the presence of BF3 etherate have been examined.In all cases, the reactions were regiospecific, resulting in incorporation of a 3-methylprop-1-
