106943-98-0Relevant academic research and scientific papers
CuI/DMPAO-catalyzed N-arylation of acyclic secondary amines
Zhang, Yu,Yang, Xinye,Yao, Qizheng,Ma, Dawei
supporting information; experimental part, p. 3056 - 3059 (2012/07/28)
DMPAO has been found to be a powerful ligand to enable copper-catalyzed coupling of aryl halides with aliphatic acyclic secondary amines take place under relatively mild conditions, and coupling of aryl halides with primary amines and cyclic secondary amines proceeds at low catalyst loading.
Acid Catalyzed α-Alkylation of β-Aminothiophenes Using Aldehydes and Selenophenol. Synthesis of Bis(3-amino-2-thienyl)methane Derivatives
Outurquin, Francis,Paulmier, Claude
, p. 5715 - 5718 (2007/10/02)
The acid-catalyzed reaction between β-aminothiophenes and aldehydes, in the presence of selenophenol, leads to α-alkyl β-aminothiophenes.The reduction step is not observed with thiophenol.Without selenol, a second alkylation reaction occurs and bis(3-amin
N-alkylation de l'amino-3 thiophene et du diamino-3,4 thiophene
Outurquin, Francis,Lerouge, Patrice,Paulmier, Claude
, p. 259 - 266 (2007/10/02)
The stable 3-(methylamino) thiophene 2a and the 3,4-bis-(methylamino)-thiophene 16a have been prepared through the reduction of the adducts formed by the condensation of formaldehyde with the 3-aminothiophene 1 and the 3,4-diaminothiophene 13.The other se
