107146-03-2Relevant academic research and scientific papers
THE INVENTION OF NEW RADICAL CHAIN REACTIONS. PART XIII. GENERATION AND REACTIVITY OF PERFLUOROALKYL RADICALS FROM THIOHYDROXAMIC ESTERS
Barton, Derek H. R.,Lacher, Brigitte,Zard, Samir Z.
, p. 2325 - 2328 (2007/10/02)
The perfluoro acid esters of N-hydroxypyridine 2-thione give perfluoroalkyl radicals on irradiation.Without any trap the radicals participate in a decarboxylative rearrangement to give 2-perfluoroalkylthiopyridines in excellent yield.In the presence of an appropriate trap, such as an electron rich olefin, adducts are formed in variable yield.
