107171-98-2

Upstream product

• 107099-13-8 Benzoic acid (2E,6E)-(1S,10R,14R)-10-bromo-14-isopropenyl-7,11-dimethyl-15-oxa-bicyclo[9.3.1]pentadeca-2,6-dien-3-ylmethyl ester 
• 86838-72-4 rel-(1R,2S)-(3E,7E,11E)-1-isopropenyl-4-<(benzoyloxy)methyl>-8,12-dimethyl-3,7,11-cyclotetradecatrien-2-ol 
• 86848-71-7 Methanesulfonic acid (5E,9E)-(1R,13S,14S)-13-isopropenyl-6,10-dimethyl-2-methylene-14-trimethylsilanyloxy-cyclotetradeca-5,9-dienyl ester 
• 86838-67-7 (6E,10E)-(1S,2R,3S,14S)-3-Isopropenyl-6,10,14-trimethyl-15-oxa-bicyclo[12.1.0]pentadeca-6,10-dien-2-ol 
• 86853-12-5 (6E,10E)-(1S,2S,3S,14S)-3-Isopropenyl-6,10,14-trimethyl-15-oxa-bicyclo[12.1.0]pentadeca-6,10-dien-2-ol 
• 59664-63-0 Mayol 
• 107171-91-5 (6E,10E)-(1S,2R,3R)-3-Isopropenyl-6,10-dimethyl-14-methylene-cyclotetradeca-6,10-diene-1,2-diol 
• 86838-70-2 Methanesulfonic acid (5E,9E)-(1R,13S,14S)-14-hydroxy-13-isopropenyl-6,10-dimethyl-2-methylene-cyclotetradeca-5,9-dienyl ester 
• 107099-13-8 Benzoic acid (2E,6E)-(1R,10R,11R,14S)-10-bromo-14-isopropenyl-7,11-dimethyl-15-oxa-bicyclo[9.3.1]pentadeca-2,6-dien-3-ylmethyl ester 
• 86838-72-4 Benzoic acid (1Z,7E,11E)-(3R,4S)-3-hydroxy-4-isopropenyl-7,11-dimethyl-cyclotetradeca-1,7,11-trienylmethyl ester 
• 107099-08-1 (6E,10E)-(1R,3S,14S)-3-Isopropenyl-6,10,14-trimethyl-15-oxa-bicyclo[12.1.0]pentadeca-6,10-dien-2-one 

Downstream Products

• 64180-67-2 (+/-)-asperdiol 

Relevant academic research and scientific papers

Cyclization of Polyenes. 46. Synthesis of (+/-)-Asperdiol, an Anticancer Cembrenoid

On the basis of retrosynthetic perspective (Scheme I), the asperdiol skeleton (I = 24) and its geometrical isomer (II = 25) were constructed from cis- and trans-isopropenyl alcohols 3a and 3b.I(24) was converted into (+/-)-asperdiol 1 by the sequential re