86838-72-4

Upstream product

• 59664-63-0 Mayol 
• 107099-08-1 (6E,10E)-(1R,3S,14S)-3-Isopropenyl-6,10,14-trimethyl-15-oxa-bicyclo[12.1.0]pentadeca-6,10-dien-2-one 
• 86838-70-2 Methanesulfonic acid (5E,9E)-(1R,13S,14S)-14-hydroxy-13-isopropenyl-6,10-dimethyl-2-methylene-cyclotetradeca-5,9-dienyl ester 
• 107171-91-5 (6E,10E)-(1S,2R,3R)-3-Isopropenyl-6,10-dimethyl-14-methylene-cyclotetradeca-6,10-diene-1,2-diol 
• 86853-12-5 (6E,10E)-(1S,2S,3S,14S)-3-Isopropenyl-6,10,14-trimethyl-15-oxa-bicyclo[12.1.0]pentadeca-6,10-dien-2-ol 
• 86838-67-7 (6E,10E)-(1S,2R,3S,14S)-3-Isopropenyl-6,10,14-trimethyl-15-oxa-bicyclo[12.1.0]pentadeca-6,10-dien-2-ol 
• 86848-71-7 Methanesulfonic acid (5E,9E)-(1R,13S,14S)-13-isopropenyl-6,10-dimethyl-2-methylene-14-trimethylsilanyloxy-cyclotetradeca-5,9-dienyl ester 
• 65-85-0 benzoic acid 
• 100572-53-0 <(4E,8E)-5,9-dimethyl-10-<(tert-butyldimethylsilyl)oxy>-4,8-decadienyl>triphenylphosphonium iodide 
• 100572-57-4 ((2E,6E,10E)-(12S,13R)-13-Benzenesulfonylmethyl-12-benzyloxy-10-benzyloxymethyl-2,6,14-trimethyl-pentadeca-2,6,10,14-tetraenyloxy)-tert-butyl-dimethyl-silane 
• 100572-60-9 C₄₀H₄₉IO₄S 
• 100572-59-6 C₄₀H₄₉BrO₄S 
• 100572-58-5 rel-(12R,13S)-(2E,6E,10E)-2,6-dimethyl-10-<(benzyloxy)methyl>-12-(benyloxy)-13-isopropenyl-14-(phenylsulfonyl)-2,6,10-tetradecatrien-1-ol 
• 100572-61-0 rel-(1R,2S)-(3E,7E,11E)-1-isopropenyl-2-(benzyloxy)-4-<(benzyloxy)methyl>-8,12-dimethyl-14-(phenylsulfonyl)-3,7,11-cyclotetradecatriene 

Downstream Products

• 107099-14-9 Benzoic acid (E)-(1R,2R,5S,7S,12R,13S)-2-bromo-13-isopropenyl-1,5-dimethyl-6,16-dioxa-tricyclo[10.3.1.0^5,7]hexadec-10-en-10-ylmethyl ester 
• 107171-98-2 Benzoic acid (E)-(1S,2S,5S,7S,12S,13R)-2-bromo-13-isopropenyl-1,5-dimethyl-6,16-dioxa-tricyclo[10.3.1.0^5,7]hexadec-10-en-10-ylmethyl ester 
• 107114-68-1 C₃₄H₄₀O₅ 
• 107099-15-0 C₃₄H₄₀O₄ 
• 107099-13-8 Benzoic acid (2E,6E)-(1S,10R,14R)-10-bromo-14-isopropenyl-7,11-dimethyl-15-oxa-bicyclo[9.3.1]pentadeca-2,6-dien-3-ylmethyl ester 
• 107099-14-9 Benzoic acid (E)-(2R,5S,7S,12S,13R)-2-bromo-13-isopropenyl-1,5-dimethyl-6,16-dioxa-tricyclo[10.3.1.0^5,7]hexadec-10-en-10-ylmethyl ester 
• 107099-14-9 Benzoic acid (E)-(2S,5S,7S,12R,13S)-2-bromo-13-isopropenyl-1,5-dimethyl-6,16-dioxa-tricyclo[10.3.1.0^5,7]hexadec-10-en-10-ylmethyl ester 
• 64180-67-2 (+/-)-asperdiol 
• 107099-13-8 Benzoic acid (2E,6E)-(1R,10R,11R,14S)-10-bromo-14-isopropenyl-7,11-dimethyl-15-oxa-bicyclo[9.3.1]pentadeca-2,6-dien-3-ylmethyl ester 

Relevant academic research and scientific papers

Cyclization of Polyenes. 46. Synthesis of (+/-)-Asperdiol, an Anticancer Cembrenoid

On the basis of retrosynthetic perspective (Scheme I), the asperdiol skeleton (I = 24) and its geometrical isomer (II = 25) were constructed from cis- and trans-isopropenyl alcohols 3a and 3b.I(24) was converted into (+/-)-asperdiol 1 by the sequential re

Synthesis of 7(8)-Deoxyasperdiol. A Precursor of the Cembranoid Asperdiol

A convergent and highly stereoselective synthesis of 7(8)-desoxyasperdiol, a 14-membered synthetic precursor of the cembranoid asperdiol, is described starting from geraniol and the epoxide of cis-2-butene-1,4-diol acetonide (A1).The route from the gerany