107271-16-9

Basic information

• Product Name: C₁₉H₂₄OSi
• CAS NO: 107271-16-9
• Molecular Weight: 296.484
• Mol File: 107271-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₉H₂₄OSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₂₄OSi(107271-16-9)
• EPA Substance Registry System: C₁₉H₂₄OSi(107271-16-9)

Safety Data

• Hazardous Substances Data: 107271-16-9(Hazardous Substances Data)

Upstream product

• 106-38-7 para-bromotoluene 
• 93-55-0 1-phenyl-propan-1-one 
• 75-77-4 chloro-trimethyl-silane 
• 107271-15-8 1-phenyl-2-p-tolylpropan-1-one 

Relevant articles and documents

Chiral bronsted acid from a cationic gold(I) complex: Catalytic enantioselective protonation of silyl enol ethers of ketones

A chiral Bronsted acid has been developed from a cationic gold(I) disphosphine complex in the presence of alcoholic solvent and applied to the enantioselective protonation reaction of silyl enol ethers of ketones. Various optically active cyclic ketones were obtained in excellent yields and high enantioselectivities, including cyclic ketones bearing aliphatic substrates at the α-position. Furthermore, the application of this Bronsted acid was extended to the first Bronsted acid-catalyzed enantioselective protonation reaction of silyl enol ethers of acyclic substrates, regardless of their E/Z ratio.