1074-28-8Relevant academic research and scientific papers
Microwave-assisted Lewis acid catalysis: Application to the synthesis of alkyl- or arylhalogermanes
Laurent, Régis,Laporterie, André,Dubac, Jacques,Berlan, Jacques
, p. 2493 - 2495 (2008/10/08)
Under microwave irradiation, alkyl- or arylhalogermanes RnGeX4-n (R = Et, Bu, Ph; X = Cl, Br) are obtained by redistribution reactions of R4Ge with GeX4. These experimental conditions permit the synthesis of such compounds in good yield in a few minutes at atmospheric pressure. The direct Friedel-Crafts germylation of benzene and toluene by germanium tetrachloride also has been performed, but yields were low.
SYNTHESE DE COMPOSES A LIAISON MIVB-MERCURE. PRECURSEURS D'ESPECES MONOVALENTES (GERMYNES), ET BIVALENTES (GERMYLENES), DE RADICAUX CENTROMETALLES ET D'INTERMEDIAIRES
Riviere, P.,Castel, A.,Satge, J.
, p. 351 - 367 (2007/10/02)
Polynuclear germyl-mercury compounds are obtained from the reaction of organohydrogermanes PhnGeH4-n or digermanes Ph2nGe2H4-n (n = 1, 2) with dialkylmercury R2Hg.Di- or tri-mercurated geminal polygermates thus synthesized generally present a low stability and undergo thermal- or photodecompositions leading to the corresponding monovalent (germynes), divalent (germylenes) or, trivalent (germanium centered radicals) species and also to intermediate biradicals which could be considered as limit forms of germanium doubly-bonded compounds .Such intermediates have been chemically and spectroscopically characterized.Extension of these reactions to the silicon analogs met with difficulties, and thus previously observed differences between silicon and germanium chemistry were confirmed.
