107400-61-3Relevant academic research and scientific papers
Diastereoselective Synthesis of Protected Syn 1,3-Diols by Base-Catalyzed Intramolecular Conjugate Addition of Hemiacetal-Derived Alkoxide Nucleophiles
Evans, David A.,Gauchet-Prunet, Joelle A.
, p. 2446 - 2453 (1993)
Reaction of the illustrated unsaturated hydroxy esters (X = OMe, R2 = H, Me) and amides (X = N(Me)OMe, R2 = H, Me) with benzaldehyde and potassium alkoxide or amide bases is reported.The resulting benzylidene acetals are obtained in
Stereoselective Reduction of δ-Hydroxy-β-ketoesters
Kathawala, Faizulla G.,Prager, Bernhard,Prasad, Kapa,Repic, Oljan,Shapiro, Michael J.,et al.
, p. 803 - 805 (2007/10/02)
The reduction of δ-hydroxy-β-ketoesters 1 was investigated with three different reducing agents.In several instances, high selectivity in favor of syn-1,3-diols was observed.
