107454-94-4

Upstream product

• 135419-20-4 3-Benzenesulfonyl-2-methyl-cyclohex-2-enol 
• 135419-25-9 2-Benzenesulfonyl-1-methyl-7-oxa-bicyclo[4.1.0]heptane 
• 1193-55-1 2-methylcyclohexane-1,3-dione 
• 64740-94-9 2-methyl-1-cyclohexenyl phenyl sulfone 
• 873-55-2 sodium benzenesulfonate 
• 118527-01-8 Methanesulfonic acid 2-methyl-3-oxo-cyclohex-1-enyl ester 
• 135419-19-1 (2-Methyl-cyclohex-2-enesulfonyl)-benzene 
• 135419-28-2 3-Benzenesulfonyl-2-methyl-cyclohex-2-enone 

Downstream Products

• 135419-27-1 3-Benzenesulfonyl-2-hydroxymethyl-cyclohex-2-enol 
• 135419-23-7 8-Benzenesulfonyl-1-oxa-spiro[2.5]octan-4-ol 

Relevant academic research and scientific papers

Controlled endocyclic and exocyclic-γ-metalations of β-substituted cyclohexenyl sulfones. Regiospecific syntehses of γ-oxygenated cyclohexenyl sulfones.

β-Substituted cyclohexenyl sulfones may be regiospecifically isomerized to either endocyclic or exocyclic allyl sulfones. Epoxidation of these materials followed by a second metalation yields γ-hydroxy cyclohexenyl sulfones 6 and 7. Subjection of either o