135419-28-2Relevant academic research and scientific papers
Comparison of vinyl organolithium and organopalladium reagents for intramolecular conjugate addition to vinyl sulfones
Lee,Fuchs
, p. 5209 - 5212 (2007/10/02)
Synthesis of cis-fused bicyclic ethers (5-10) by intramolecular conjugate addition of vinyl lithium and organopalladium reagents to cyclohexenyl/pentenyl moiety of vinyl sulfones is described.
Controlled endocyclic and exocyclic-γ-metalations of β-substituted cyclohexenyl sulfones. Regiospecific syntehses of γ-oxygenated cyclohexenyl sulfones.
lee,Fuchs
, p. 2861 - 2864 (2007/10/02)
β-Substituted cyclohexenyl sulfones may be regiospecifically isomerized to either endocyclic or exocyclic allyl sulfones. Epoxidation of these materials followed by a second metalation yields γ-hydroxy cyclohexenyl sulfones 6 and 7. Subjection of either o
