107487-40-1

Upstream product

• 67-56-1 methanol 
• 855624-42-9 4-bromo-3-nitro-1,4-diphenyl-butan-1-one 
• 88430-52-8 1,4-diphenylbutadiene monoepoxide 
• 1743-36-8 1-phenylbut-3-yn-1-ol 
• 70672-97-8 (1-methoxybut-3-yn-1-yl)benzene 
• 100-52-7 benzaldehyde 
• 1198597-24-8 (4-methoxybut-1-yne-1,4-diyl)dibenzenene 

Downstream Products

• 1030-09-7 (E)-4-methoxy-1,4-diphenylbut-2-en-1-ol 

Relevant academic research and scientific papers

Gold-catalyzed oxidative rearrangement of homopropargylic ether via oxonium ylide

Synthetically useful α,β-unsaturated carbonyl compounds were obtained from gold-catalyzed oxidative rearrangement of homopropargylic ether under mild reaction conditions. Gold carbenoid and oxonium ylide are proposed as key intermediates.

Nucleophilic Attack on a Carbonyl Group Conjugated to a Chiral Centre: A Search For a Vinylogous Cram's Rule

In a search for a vinylogous version of Cram's rule, 1,4-diphenylbut-2-ene-1,4-dione (5), 4-methoxy-1,4-diphenylbut-2-en-1-one (9), and hex-3-ene-2,5-dione (13) are found to be reduced with low or negligible diastereoselectivity.Similarly, the phenyl Grignard reagent showed no diastereoselectivity in its reaction with 4-methoxy-4-phenylbut-2-enal (12)