107535-96-6Relevant academic research and scientific papers
Neighboring Carbonyl Group Assisted Hydration of Unsymmetrical Aryl Alkynes Overriding Regular Selectivity
Mendhekar, Kishor L.,Pradhan, Tapas R.,Mallampudi, N. Arjunreddy,Mohapatra, Debendra K.
, p. 5787 - 5797 (2019/08/21)
A mild and highly regioselective gold-catalyzed hydration of γ-acetoxy aryl alkynes leading to anti-Markovnikov products by the assistance of a neighboring carbonyl group is presented. The reaction procedure operates under room temperature conditions with
A VERSATILE REAGENT FOR SYNTHESIS OF α-HYDROXY ALDEHYDES AND KETONES --- METHYLTHIOMETHYL p-TOLYL SULFONE
Ogura, Katsuyuki,Tsuruda, Toshihiko,Takahashi, Kazumasa,Iida, Hirotada
, p. 3665 - 3668 (2007/10/02)
Methylthiomethyl p-tolyl sulfone (1) can be utilized for synthesizing α-hydroxy ketones as well as α-hydroxy aldehydes, the hydroxyl group of which is protected with acetyl, tetrahydropyranyl, or methoxymethyl group.
