107657-73-8

Upstream product

• 155732-68-6 1-methylprop-1-enylmagnesium bromide 
• 110510-54-8 (+/-)-(2S^*,3R^*)-3-(benzyloxy)-2-<(2-methoxyethoxy)methoxy>-2-methyl-1-butanal 
• 113133-46-3 3-(phenylmethoxy)butan-2-one 
• 110510-53-7 (+/-)-(3R^*,4R^*)-4-(benzyloxy)-3-<(2-methoxyethoxy)methoxy>-3-methyl-1-pentene 
• 98095-59-1 (+/-)-(3R^*,4R^*)-4-(benzyloxy)-3-methyl-1-penten-3-ol 

Downstream Products

• 98095-65-9 Benzoic acid (2S,3R,4R,5S)-2-((S)-1-iodo-ethyl)-4-(2-methoxy-ethoxymethoxy)-2,4,5-trimethyl-tetrahydro-furan-3-yl ester 
• 98095-66-0 (+/-)-(2S^*,3R^*,4S^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2-vinyl-3-tetrahydrofuranyl benzoate 
• 98168-77-5 (+/-)-(2S^*,3S^*,4S^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2-vinyl-3-tetrahydrofuranyl benzoate 
• 94120-02-2 (+/-)-citoreoviral 
• 110510-59-3 (+/-)-(2S^*,3S^*,4S^*,5R^*)-3-(benzoyloxy)-2-<2-carbethoxy-1(E)-propenyl>-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2,3,4,5-tetrahydrofuran 
• 110510-57-1 (+/-)-(2S^*,3S^*,4S^*,5R^*)-2-formyl-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-3-tetrahydrofuranyl benzoate 
• 107613-13-8 Benzoic acid (Z)-(S)-1-[(1R,2S)-2-benzyloxy-1-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-but-2-enyl ester 

Relevant academic research and scientific papers

Total Synthesis of (+/-)-Citreoviridin

Investigations of iodine-induced cyclizations of γ,δ-olefinic benzyl ethers have led to highly substituted tetrahydrofurans from acyclic precursors with excellent stereochemical control.Our studies have afforded total syntheses of two fungal metabolites,

HYDROXYL-DIRECTED IODOETHERIFICATIONS OF ALLYLIC ALCOHOLS. SYNTHESIS OF ALLYLIC ALCOHOLS. SYNTHESSIS OF (+/-)-CITREOVIRAL.

Iodine-induced cyclizations of γ,δ-olefinic benzyl ethers have afforded highly substituted tetrahydrofurans with complete stereocontrol as directed by the configuration of an allylic alcohol.Evidence for stereochemical assignments and conversion to citreo