98168-77-5

Upstream product

• 107657-73-8 (Z)-(4S,5S,6S)-6-Benzyloxy-5-(2-methoxy-ethoxymethoxy)-3,5-dimethyl-hept-2-en-4-ol 
• 98095-59-1 (+/-)-(3R^*,4R^*)-4-(benzyloxy)-3-methyl-1-penten-3-ol 
• 98095-63-7 (+/-)-(2R^*,3S^*,4S^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2-(1-iodoethyl)-2,4,5-trimethyl-3-tetrahydrofuranol 
• 107613-13-8 Benzoic acid (Z)-(R)-1-[(1R,2S)-2-benzyloxy-1-(2-methoxy-ethoxymethoxy)-1-methyl-propyl]-2-methyl-but-2-enyl ester 
• 98-88-4 benzoyl chloride 
• 98168-76-4 (+/-)-(2S^*,3S^*,4R^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2-vinyl-3-tetrahydrofuranol 
• 98095-68-2 (+/-)-(2S^*,4S^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2-vinyl-3-tetrahydrofuranone 
• 98095-67-1 (+/-)-(2S^*,3R^*,4R^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2-vinyl-3-tetrahydrofuranol 
• 98095-63-7 (2S,3R,4S,5S)-2-((S)-1-Iodo-ethyl)-4-(2-methoxy-ethoxymethoxy)-2,4,5-trimethyl-tetrahydro-furan-3-ol 
• 110510-54-8 (+/-)-(2S^*,3R^*)-3-(benzyloxy)-2-<(2-methoxyethoxy)methoxy>-2-methyl-1-butanal 
• 110510-53-7 (+/-)-(3R^*,4R^*)-4-(benzyloxy)-3-<(2-methoxyethoxy)methoxy>-3-methyl-1-pentene 
• 110510-55-9 (2S,4R,5S)-2-((S)-1-Iodo-ethyl)-4-(2-methoxy-ethoxymethoxy)-2,4,5-trimethyl-dihydro-furan-3-one 
• 98095-65-9 (+/-)-(2R^*,3S^*,4S^*,5R^*)-4-<(2-methoxyethoxy)methoxy>-2-(1-iodoethyl)-2,4,5-trimethyl-3-tetrahydrofuranyl benzoate 

Downstream Products

• 94120-02-2 (+/-)-citoreoviral 
• 110510-61-7 (+/-)-(2S^*,3S^*,4S^*,5R^*)-3-(benzoyloxy)-2-<2-carbethoxy-1(E)-propenyl>-2,4,5-trimethyl-2,3,4,5-tetrahydrofuran-4-ol 
• 110510-67-3 (+/-)-epicitreoviral 
• 110510-68-4 (+/-)-(2S^*,3R^*,4S^*,5R^*)-2-(2-formyl-1(E)-propenyl)-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2,3,4,5-tetrahydrofuran-3-ol 
• 97514-85-7 (+/-)-citreoviral 
• 110510-59-3 (+/-)-(2S^*,3S^*,4S^*,5R^*)-3-(benzoyloxy)-2-<2-carbethoxy-1(E)-propenyl>-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-2,3,4,5-tetrahydrofuran 
• 110510-57-1 (+/-)-(2S^*,3S^*,4S^*,5R^*)-2-formyl-4-<(2-methoxyethoxy)methoxy>-2,4,5-trimethyl-3-tetrahydrofuranyl benzoate 

Relevant academic research and scientific papers

Total Synthesis of (+/-)-Citreoviridin

Investigations of iodine-induced cyclizations of γ,δ-olefinic benzyl ethers have led to highly substituted tetrahydrofurans from acyclic precursors with excellent stereochemical control.Our studies have afforded total syntheses of two fungal metabolites,

HYDROXYL-DIRECTED IODOETHERIFICATIONS OF ALLYLIC ALCOHOLS. SYNTHESIS OF ALLYLIC ALCOHOLS. SYNTHESSIS OF (+/-)-CITREOVIRAL.

Iodine-induced cyclizations of γ,δ-olefinic benzyl ethers have afforded highly substituted tetrahydrofurans with complete stereocontrol as directed by the configuration of an allylic alcohol.Evidence for stereochemical assignments and conversion to citreo