107730-81-4Relevant academic research and scientific papers
Intermediates in the Palladium-Catalysed Reactions of 1,3-Dienes, Part 5. Butadiene Complexes of Nickel, Palladium and Platinum
Benn, R.,Jolly, P. W.,Joswig, T.,Mynott, R.,Schick, K.-P.
, p. 680 - 691 (2007/10/02)
A series of complexes of Ni, Pd and Pt has been prepared and their structures investigated NMR-spectroscopically.The nickel and palladium complexes, irrespective of the substituents at phosphorus, contain a fluxional η2-bonded butadiene molecule.In the case of platinum the bonding mode is ligand dependent: an η2-arrangement is observed where R is tert-butyl or cyclohexyl while when R is isopropyl the butadiene adopts an η1,η1-arrangement to give a platinacyclopentene derivative. - Keywords: Nickel-organo Complex, Palladium-organo Complex, Platinum-organo Complex, Butadiene Complex
