107730-84-7Relevant academic research and scientific papers
Stable bis(silyl)palladium complexes: Synthesis, structure, and bis-silylation of acetylenes
Pan, Youlin,Mague, Joel T.,Fink, Mark J.
, p. 3495 - 3497 (1992)
A class of unusually stable bis(silyl)palladium complexes is prepared by the reaction of a dinuclear Pd(I) hydride with either simple hydrosilanes or disilanes. The first structure of a palladium bis(silyl) compound and preliminary reaction chemistry with acetylenes are reported.
Intermediates in the Palladium-Catalysed Reactions of 1,3-Dienes, Part 5. Butadiene Complexes of Nickel, Palladium and Platinum
Benn, R.,Jolly, P. W.,Joswig, T.,Mynott, R.,Schick, K.-P.
, p. 680 - 691 (2007/10/02)
A series of complexes of Ni, Pd and Pt has been prepared and their structures investigated NMR-spectroscopically.The nickel and palladium complexes, irrespective of the substituents at phosphorus, contain a fluxional η2-bonded butadiene molecule.In the case of platinum the bonding mode is ligand dependent: an η2-arrangement is observed where R is tert-butyl or cyclohexyl while when R is isopropyl the butadiene adopts an η1,η1-arrangement to give a platinacyclopentene derivative. - Keywords: Nickel-organo Complex, Palladium-organo Complex, Platinum-organo Complex, Butadiene Complex
