107730-84-7

Upstream product

• 107730-81-4 [Pd((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)(C₄H₆)] 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 141319-65-5 Pd(C₂O₄)(1,2-bis(dicyclohexylphosphino)ethane) 
• 148572-28-5 {(μ2-1,2-bis(dicyclohexylphosphino)ethane)palladium(0)}2 

Relevant academic research and scientific papers

Stable bis(silyl)palladium complexes: Synthesis, structure, and bis-silylation of acetylenes

A class of unusually stable bis(silyl)palladium complexes is prepared by the reaction of a dinuclear Pd(I) hydride with either simple hydrosilanes or disilanes. The first structure of a palladium bis(silyl) compound and preliminary reaction chemistry with acetylenes are reported.

Intermediates in the Palladium-Catalysed Reactions of 1,3-Dienes, Part 5. Butadiene Complexes of Nickel, Palladium and Platinum

A series of complexes of Ni, Pd and Pt has been prepared and their structures investigated NMR-spectroscopically.The nickel and palladium complexes, irrespective of the substituents at phosphorus, contain a fluxional η2-bonded butadiene molecule.In the case of platinum the bonding mode is ligand dependent: an η2-arrangement is observed where R is tert-butyl or cyclohexyl while when R is isopropyl the butadiene adopts an η1,η1-arrangement to give a platinacyclopentene derivative. - Keywords: Nickel-organo Complex, Palladium-organo Complex, Platinum-organo Complex, Butadiene Complex