107785-13-7Relevant academic research and scientific papers
Structural and Mechanistic Insights into s-Block Bimetallic Catalysis: Sodium Magnesiate-Catalyzed Guanylation of Amines
De Tullio, Marco,Hernán-Gómez, Alberto,Livingstone, Zoe,Clegg, William,Kennedy, Alan R.,Harrington, Ross W.,Anti?olo, Antonio,Martínez, Antonio,Carrillo-Hermosilla, Fernando,Hevia, Eva
, p. 17646 - 17656 (2016)
To advance the catalytic applications of s-block mixed-metal complexes, sodium magnesiate [NaMg(CH2SiMe3)3] (1) is reported as an efficient precatalyst for the guanylation of a variety of anilines and secondary amines with
Catalytic guanylation of aliphatic, aromatic, heterocyclic primary and secondary amines using nanocrystalline zinc(II) oxide
Kantam, M. Lakshmi,Priyadarshini,Amal Joseph,Srinivas,Vinu,Klabunde,Nishina, Yuta
experimental part, p. 5730 - 5737 (2012/09/08)
Nanocrystalline ZnO was found to be a highly efficient heterogeneous catalyst for the guanylation of amines with various carbodiimides to afford N,N′,N″-trisubstituted guanidines in excellent yields. Structurally divergent aliphatic, aromatic, heterocyclic primary and secondary amines were converted to the corresponding N,N′,N″-trisubstituted guanidines using optimal conditions. The catalyst was easy to handle even under atmospheric conditions and can be easily recovered by centrifugation and reused for five cycles with consistent activity.
Rare-earth metal tris(trimethylsilylmethyl) anionic complexes bearing one 1-phenyl-2,3,4,5-tetrapropylcyclopentadienyl ligand: Synthesis, structural characterization, and application
Xu, Ling,Wang, Zitao,Zhang, Wen-Xiong,Xi, Zhenfeng
, p. 11941 - 11948,8 (2020/10/15)
Synthesis and structural characterization of half-sandwich rare-earth metal tris(trimethylsilylmethyl) anionic complexes bearing one 1-phenyl-2,3,4,5- tetrapropylcyclopentadienyl ligand are achieved. These soluble anionic compounds show good reactivity in
Synthesis of acylguanidine analogues: inhibitors of ADP-induced platelet aggregation
Thomas,Nishizawa,Zimmermann,Williams
, p. 228 - 236 (2007/10/02)
Routine screening of compounds for inhibition of ADP-induced platelet aggregation in vitro revealed that 1'-hexamethylenebis[3-cyclohexyl-3-[(cyclohexylimino)(4-morpholinyl)methyl] urea] was active and represented the first example of a bis(acylguanidine) with possible antithrombotic activity. In order to develop a structure-activity relationship for this class of compounds, we synthesized a number of new bis(acylguanidines). These were tested in vitro, and several analogues were also active. Ex vivo testing revealed that compounds 22, 41, 58, and 70-73 were orally active in rats or guinea pigs.
