107824-82-8

Basic information

• Product Name: 2,3-benzo-1,4,5,6,7,7-hexaphenyl-7-germanorborna-2,5-diene
• CAS NO: 107824-82-8
• Molecular Weight: 659.366
• Mol File: 107824-82-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-benzo-1,4,5,6,7,7-hexaphenyl-7-germanorborna-2,5-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-benzo-1,4,5,6,7,7-hexaphenyl-7-germanorborna-2,5-diene(107824-82-8)
• EPA Substance Registry System: 2,3-benzo-1,4,5,6,7,7-hexaphenyl-7-germanorborna-2,5-diene(107824-82-8)

Safety Data

• Hazardous Substances Data: 107824-82-8(Hazardous Substances Data)

Upstream product

• 546-67-8 lead(IV) tetraacetate 
• 15922-94-8 1,1,2,3,4,5-hexaphenylgermacyclopentadiene 
• 1614-12-6 1H-1,2,3-benzotriazol-1-amine 

Downstream Products

• 751-38-2 1,2,3,4-tetraphenylnaphthalene 
• 5764-69-2 1,1-diphenyl-3,4-dimethyl-1-germacyclopent-3-ene 
• 110889-96-8 4-alkylidene-1,2,3-thiadigermetane 
• 107824-83-9 C₁₀H₁₄(SH)(Ge(C₆H₅)2OC₂H₅) 
• 115560-31-1 diphenylgermylene (2-methyl)tetrahydrofuran complex 
• 115560-27-5 diphenylgermylene THT complex 
• 115560-23-1 diphenylgermylene dimethylsulfide complex 
• 68816-03-5 diphenylgermylene 

Relevant articles and documents

Synthesis and chemistry of thiagermiranes

Dimethylgermylene (1) reacts with thioketones 3 and 9 to give 1,3,2,4-dithiadigermolanes 4 and 10, the ultimate products of formation of thiagermiranes 6 and 11 and subsequent addition of dimethylgermanethione (7). Dimesitylgermylene (16) reacts with adamantanethione (3) to give 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (18). Photolysis of thiagermirane 18 yields dimesitylgermylene (16) and adamantanethione (3) derived from germathiocarbonyl ylide 22. Oxidation of thiagermirane 18 by mCPBA gives 3-(2-adamantyl)-4,4-dimesityl-1,2,4-oxathiagermetane S-oxide (27). X-ray analyses were done for thiagermirane 18 and 1,2,4-oxathiagermetane S-oxide 27.