107824-83-9

Upstream product

• 23695-65-0 adamantane-2-thione 
• 107824-82-8 2,3-benzo-1,4,5,6,7,7-hexaphenyl-7-germanorborna-2,5-diene 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 107824-85-1 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane 
• 122967-96-8 C₁₀H₁₄SGe(C₆H₂(CH₃)3)2 
• 15922-94-8 1,1,2,3,4,5-hexaphenylgermacyclopentadiene 

Relevant academic research and scientific papers

Synthesis and chemistry of thiagermiranes

Dimethylgermylene (1) reacts with thioketones 3 and 9 to give 1,3,2,4-dithiadigermolanes 4 and 10, the ultimate products of formation of thiagermiranes 6 and 11 and subsequent addition of dimethylgermanethione (7). Dimesitylgermylene (16) reacts with adamantanethione (3) to give 3-(2-adamantyl)-2,2-dimesityl-1,2-thiagermirane (18). Photolysis of thiagermirane 18 yields dimesitylgermylene (16) and adamantanethione (3) derived from germathiocarbonyl ylide 22. Oxidation of thiagermirane 18 by mCPBA gives 3-(2-adamantyl)-4,4-dimesityl-1,2,4-oxathiagermetane S-oxide (27). X-ray analyses were done for thiagermirane 18 and 1,2,4-oxathiagermetane S-oxide 27.