107839-99-6

Basic information

• Product Name: (2,2-difluoro-1-phenylvinyl)trimethylsilane
• Synonyms: (2,2-difluoro-1-phenylvinyl)trimethylsilane
• CAS NO: 107839-99-6
• Molecular Weight: 212.314
• Mol File: 107839-99-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2,2-difluoro-1-phenylvinyl)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (2,2-difluoro-1-phenylvinyl)trimethylsilane(107839-99-6)
• EPA Substance Registry System: (2,2-difluoro-1-phenylvinyl)trimethylsilane(107839-99-6)

Safety Data

• Hazardous Substances Data: 107839-99-6(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 74492-30-1 α-bromo-β,β-difluorostyrene 
• 874761-91-8 α-iodo-β,β-difluorostyrene 
• 75-77-4 chloro-trimethyl-silane 
• 591-50-4 iodobenzene 
• 1569101-80-9 2,2-difluoro-1-(trimethylsilyl)ethenyltributylstannane 
• 501649-41-8 2,2-difluoro-1-(trimethylsilyl)ethenyl p-toluenesulfonates 
• 1421521-50-7 (2,2-difluoro-1-iodovinyl)trimethylsilane 
• 98-80-6 phenylboronic acid 

Downstream Products

• 405-42-5 2',2'-difluorostyrene 
• 107840-00-6 5-fluoro-1,4-diphenyl-1,2,3-triazole 
• 1112153-73-7 (Z)-(2-fluoro-1-phenylhex-1-enyl)trimethylsilane 
• 1112153-78-2 ((E)-2-fluoro-3,3-dimethyl-1-phenylbut-1-enyl)trimethylsilane 
• 1112153-72-6 (Z)-(-2-fluoro-3,3-dimethyl-1-phenylbut-1-enyl)trimethylsilane 
• 1196894-70-8 (E)-(1-bromo-2-fluorovinyl)benzene 
• 20405-78-1 (Z)-(2-fluorovinyl)benzene 
• 20405-77-0 (E)-(2-fluorovinyl)benzene 

Relevant articles and documents

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Efficient synthesis of silylated 2,2-difluorostyrene derivatives through Suzuki-Miyaura cross-coupling of 2,2-difluoro-1-iodo-1-silylethenes

We report a new synthetic sequence for the preparation of silylated 2,2-difluorostyrene derivatives. This new route has numerous advantages over the previous one including enhanced scope, higher yields, ease of purification, and significant reduction of the amount of desilylated side-products. An unexpected transformation of a silylated 2,2-difluorostyrene derivative is also presented.

Stereocontrolled approach to bromofluoroalkenes and their use for the synthesis of tri- and tetrasubstituted fluoroalkenes

(Chemical Equation Presented) An addition/elimination reaction of organolithium reagents to silylated ββf-difluorostyrene derivatives followed by a bromination/ desilicobromination reaction provides a simple and effective synthetic approach to a wide rang