874761-91-8Relevant academic research and scientific papers
The first preparation of the α-iodo-β,β-difluorovinylzinc reagent (CF2=CIZnCl) and a high-yield one-pot synthesis of α-iodo-β,β-difluorostyrenes
Anilkumar,Burton, Donald J.
, p. 457 - 463 (2005)
The α-iodo-β,β-difluorovinylzinc reagent (CF 2=CIZnCl) was synthesized in >87% yield via room-temperature metallation of the commercially available CF3CH2I with LDA in the presence of ZnCl2. This novel zinc reag
Stereoselective synthesis of both stereoisomers of β-fluorostyrene derivatives from a common intermediate
Landelle, Gregory,Turcotte-Savard, Marc-Olivier,Angers, Laetitia,Paquin, Jean-Francois
supporting information; scheme or table, p. 1568 - 1571 (2011/04/26)
The stereoselective synthesis of both cis- and trans-β-fluorostyrene derivatives from a common intermediate, (Z)-1-aryl-2-fluoro-1-(trimethylsilyl) ethenes, is described. The trans isomers are obtained by a stereospecific replacement of the silyl group in
Stereocontrolled access to unsymmetrical 1,1 -diaryl-2-fluoroethenes
Landelle, Gregory,Turcotte-Savard, Marc-Olivier,Marterer, Judikaelle,Champagne, Pier Alexandre,Paquin, Jean-Francois
supporting information; experimental part, p. 5406 - 5409 (2010/01/17)
"Chemical Equation Presented" A simple and effective method for stereocontrolled preparation of 1,1-diaryl-2-fluoroethenes is reported. First, 1-aryl-1-bromo-2-fluoroethenes are generated using an addition/elimination reaction of hydride to silylated, β,β
