107855-65-2Relevant academic research and scientific papers
Selective Palladium-Catalyzed Aminocarbonylation of Olefins to Branched Amides
Liu, Jie,Li, Haoquan,Spannenberg, Anke,Franke, Robert,Jackstell, Ralf,Beller, Matthias
, p. 13544 - 13548 (2016)
A general and efficient protocol for iso-selective aminocarbonylation of olefins with aliphatic amines has been developed for the first time. Key to the success for this process is the use of a specific 2-phosphino-substituted pyrrole ligand in the presence of PdX2(X=halide) as a pre-catalyst. Bulk industrial and functionalized olefins react with various aliphatic amines, including amino-acid derivatives, to give the corresponding branched amides generally in good yields (up to 99 %) and regioselectivities (b/l up to 99:1).
DODECACARBONYLTRIRUTHENIUM CATALYSED CARBONYLATION OF AMINES AND HYDROAMIDATION OF OLEFINS
Tsuji, Yasushi,Ohsumi, Tatsuya,Kondo Teruyuki,Watanabe, Yoshihisa
, p. 333 - 344 (2007/10/02)
Dodecacarbonyltriruthenium (Ru3(CO)12) is an effective homogeneous catalyst precursor for the carbonylation of amines and hydroamidation of olefins under a carbon monoxide pressure of 40 kg cm-2 at 120-180 deg C.By the carbonylation of benzylamine, N- benzylformamide was obtained in 77percent yield. 1-Octene was hydroamidated with benzylamine to N-benzylnonanamide in 67percent yield (the selectivity to its linear isomer was 81percent).These reactions appear to include ruthenium carbamoyl complex as the common key intermediate.
