107917-65-7

Basic information

• Product Name: 3-(2-aminophenyl)-6-chloro-1-methylquinoxalin-2(1H)-one
• Synonyms: 3-(2-aminophenyl)-6-chloro-1-methylquinoxalin-2(1H)-one
• CAS NO: 107917-65-7
• Molecular Weight: 285.733
• Mol File: 107917-65-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(2-aminophenyl)-6-chloro-1-methylquinoxalin-2(1H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-aminophenyl)-6-chloro-1-methylquinoxalin-2(1H)-one(107917-65-7)
• EPA Substance Registry System: 3-(2-aminophenyl)-6-chloro-1-methylquinoxalin-2(1H)-one(107917-65-7)

Safety Data

• Hazardous Substances Data: 107917-65-7(Hazardous Substances Data)

Upstream product

• 890136-90-0 2-(2-azidophenyl)-2-oxoacetic acid 
• 91-56-5 indole-2,3-dione 
• 59681-66-2 4-chloro-1-N-methylbenzene-1,2-diamine 
• 15950-17-1 4-chloro-N-methyl-2-nitroaniline 
• 89-63-4 4-Chloro-2-nitroaniline 
• 108897-00-3 acetic acid-[2-(7-chloro-4-methyl-3-oxo-3,4-dihydro-quinoxalin-2-yl)-anilide] 

Downstream Products

• 112550-71-7 toluene-4-sulfonic acid-[2-(7-chloro-4-methyl-3-oxo-3,4-dihydro-quinoxalin-2-yl)-N-methyl-anilide] 
• 131197-14-3 6-chloro-1-methyl-3-(2-methylamino-phenyl)-1H-quinoxalin-2-one 

Relevant articles and documents

Amino Azaxylylenes Photogenerated from o-Amido Imines: Photoassisted Access to Complex Spiro-Poly-Heterocycles

Upon irradiation, cyclic imines containing o-amido groups are shown to produce reactive intermediates, amino azaxylylenes, which undergo intramolecular cycloadditions to tethered unsaturated pendants to yield complex N,O-heterocycles having an additional spiro-connected nitrogen heterocyclic moiety. Modular assembly of the photoprecursors allows expeditious increase of the complexity of the target poly-heterocyclic scaffolds with a minimal number of experimentally simple reaction steps. The photocyclization and subsequent postphotochemical transformations are accompanied by an increase of Lovering's fsp3 factor, thus producing unprecedented three-dimensional molecular architectures, and offering extended sampling of chemical space. Rings in three dimensions: Cyclic imines containing an o-amido group undergo excited-state intramolecular proton transfer to generate amino azaxylylenes. The amino azaxylylenes undergo intramolecular cycloadditions to tethered unsaturated pendants to yield complex heterocyclic three-dimensional molecular architectures.