107940-16-9

Basic information

• Product Name: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(phenoxymethylene)-, (Z)-
• CAS NO: 107940-16-9
• Molecular Formula: C14H24O3Si2
• Molecular Weight: 296.514
• Mol File: 107940-16-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(phenoxymethylene)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(phenoxymethylene)-, (Z)-(107940-16-9)
• EPA Substance Registry System: 3,5-Dioxa-2,6-disilaheptane, 2,2,6,6-tetramethyl-4-(phenoxymethylene)-, (Z)-(107940-16-9)

Safety Data

• Hazardous Substances Data: 107940-16-9(Hazardous Substances Data)

Upstream product

• 21273-08-5 2-Phenoxyethansaeure-trimethylsilylester 
• 122-59-8 2-phenoxyacetic acid 
• 75-77-4 chloro-trimethyl-silane 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 721-04-0 2-phenoxy-1-phenylethanone 
• 133692-98-5 trimethylsilyl-4,4-dibromo-3-trimethylsiloxy-2-phenoxy-3-butenoate 
• 74590-70-8 2-fluoro-2-phenoxyacetic acid 
• 133692-97-4 trimethylsilyl-4,4-difluoro-3-trimethylsiloxy-2-phenoxy-3-butenoate 
• 71617-04-4 1-phenoxyheptan-2-one 

Relevant articles and documents

Synthesis of 7,8-benzo-9-aza-4-oxabicyclo[3.3.1]nonan-3-ones by sequential 'condensation-iodolactonization' reactions of 1,1-bis(trimethylsilyloxy)ketene acetals with isoquinolines

Functionalized 7,8-benzo-9-aza-4-oxabicyclo[3.3.1]nonan-3-ones were prepared by regio- and diastereoselective condensation of 1,1-bis(silyloxy) ketene acetals with isoquinolinium salts and subsequent regioselective and stereospecific iodolactonization.

One-pot synthesis of 3-hydroxymaleic anhydrides by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride

Functionalized 3-hydroxymaleic anhydrides were prepared by cyclization of 1,1-bis(trimethylsilyloxy)ketene acetals with oxalyl chloride.

Reactions of Trialkylsilyl Trifluoromethanesulfonates, VI. - Synthesis of 2-Heterosubstituted O-Alkyl-O-(trimethylsilyl)ketene Acetals and 2-(Trimethylsilyl)carboxylates

Organooxy- and (alkylthio)ethanoic acid esters 2 are silylated by trimethylsilyl triflate (1) in the presence of triethylamine to yield mixtures of ketene acetals 3 and 2-(trimethylsilyl)ethanoates 4.The product distributions 3/4 are governed by the ester groups and the substituents in α position.Cyclic derivatives of 2-hydroxycarboxylic acids 7,9 are silylated by 1/triethylamine to give the ketene acetals 8,10.From N-protected glycine methyl esters 11,12 the ketene acetals 13,15 are obtained in the reaction with 1/triethylamine.