107941-23-1Relevant articles and documents
Cobalt-catalyzed benzyl-alkynyl coupling
Kuno, Akiko,Saino, Naoko,Kamachi, Taku,Okamoto, Sentaro
, p. 2591 - 2594 (2006)
Benzylic halides coupled with 1-alkynylmagnesium halides in the presence of a catalytic amount of Co(acac)3 to provide 1-aryl-2-alkynes in moderate to good yield.
Ortho-Bromo(propa-1,2-dien-1-yl)arenes: Substrates for domino reactions
Masters, Kye-Simeon,Wallesch, Manuela,Braese, Stefan
experimental part, p. 9060 - 9067 (2011/12/03)
o-Bromo(propa-1,2-dien-1-yl)arenes exhibit novel and orthogonal reactivity under Pd catalysis in the presence of secondary amines to form enamines (concerted Pd insertion, intramolecular carbopalladation, and terminative Buchwald-Hartwig coupling) and of amides to form indoles (addition, Buchwald-Hartwig cyclization, and loss of the acetyl group). The substrates for these reactions can be accessed in a reliable and highly selective two-step process from 2-bromoaryl bromides.