107957-81-3

Basic information

• Product Name: 2-methyl-5-(1-methyl-ethenyl)-1-tertbutyl-diphenylsiloxycyclohexene
• Synonyms: 2-methyl-5-(1-methyl-ethenyl)-1-tertbutyl-diphenylsiloxycyclohexene
• CAS NO: 107957-81-3
• Molecular Weight: 390.641
• Mol File: 107957-81-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-methyl-5-(1-methyl-ethenyl)-1-tertbutyl-diphenylsiloxycyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-5-(1-methyl-ethenyl)-1-tertbutyl-diphenylsiloxycyclohexene(107957-81-3)
• EPA Substance Registry System: 2-methyl-5-(1-methyl-ethenyl)-1-tertbutyl-diphenylsiloxycyclohexene(107957-81-3)

Safety Data

• Hazardous Substances Data: 107957-81-3(Hazardous Substances Data)

Upstream product

• 201012-68-2 (5S)-2-methyl-5-(prop-1-en-2-yl)cyclohexan-1-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 473-08-5 eudesma-4,11-dien-3-one 
• 108032-82-2 <1S,4R>-1-methyl-1-(3-pentanone)-4-isopropenyl-2-oxocyclohexane 
• 107957-82-4 (2R,5R)-2-methyl-2-(3-oxopentyl)-5-isopropenylcyclohexan-1-one 

Relevant articles and documents

1,5-DICARBONYL COMPOUNDS A GENERAL PREPARATION METHOD

In this report, a general method for the preparation of 1,5-dicarbonyl compounds and six membered ring annelation is described.This method involves the reaction of hemiacetal vinylogs 1 with enol ethers 2 or 3 in the presence of a Lewis acid.This reaction was successfully applied to the enol ethers of α and α,α'-hindered ketones such as 2,2,6-trimethyl cyclohexanone. α-Cyperone and 6-epi-α-cyperone were obtained using this process.