107994-94-5Relevant academic research and scientific papers
Generation of silanimines by photolysis of hindered azidosilanes
Zigler, Steven S.,Johnson, Leighta M.,West, Robert
, p. 187 - 198 (1988)
Trimesitylazidosilane (1) and three new azidosilanes, Mes2Si(N3)SiPh2-t-Bu (2), Me2Si(N3)SiMes2-t-Bu (3) and i-Pr2Si(N3)SiMes2-t-Bu (4), were prepared and photolyzed at 254 nm.Compound 1 photolyzes in glassy 3-methylpentane (3-MP) at 77 K or in 3-MP solut
OBSERVATION OF A SILANIMINE IN AN INERT MATRIX AND IN SOLUTION AT LOW TEMPERATURE
Zigler, Steven S.,West, Robert,Michl, Josef
, p. 1025 - 1028 (2007/10/02)
Irradiation of Mes3SiN3 in 3-methylpentane at 77 K or -140 deg C yields the silanimine, Mes2Si=NMes.The silanimine is yellow (λmax=296, 444 nm) and decomposes at temperatures above ca. -120 deg C.
