Generation of silanimines by photolysis of hindered azidosilanes

DOI: 10.1016/0022-328X(88)89074-0

Source and publish data:

Journal of Organometallic Chemistry p. 187 - 198 (1988)

Update date:2022-07-31

Topics:

Authors:

Zigler, Steven S.

Johnson, Leighta M.

West, Robert

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Article abstract of DOI:10.1016/0022-328X(88)89074-0

Trimesitylazidosilane (1) and three new azidosilanes, Mes2Si(N3)SiPh2-t-Bu (2), Me2Si(N3)SiMes2-t-Bu (3) and i-Pr2Si(N3)SiMes2-t-Bu (4), were prepared and photolyzed at 254 nm.Compound 1 photolyzes in glassy 3-methylpentane (3-MP) at 77 K or in 3-MP solut

Full text of DOI:10.1016/0022-328X(88)89074-0

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