1080022-77-0

Basic information

• Product Name: Cu(HNC(C₆H₁₁)NC₈H₄NO)2
• CAS NO: 1080022-77-0
• Molecular Weight: 572.169
• Mol File: 1080022-77-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cu(HNC(C₆H₁₁)NC₈H₄NO)2(CAS DataBase Reference)
• NIST Chemistry Reference: Cu(HNC(C₆H₁₁)NC₈H₄NO)2(1080022-77-0)
• EPA Substance Registry System: Cu(HNC(C₆H₁₁)NC₈H₄NO)2(1080022-77-0)

Safety Data

• Hazardous Substances Data: 1080022-77-0(Hazardous Substances Data)

Upstream product

• 6046-93-1 copper(II) acetate monohydrate 
• 14352-51-3 3-iminoisoindolinone 
• 766-05-2 cyclohexane carbonitrile 

Relevant articles and documents

Copper-mediated imine-nitrile coupling leading to unsymmetric 1,3,5-triazapentadienato complexes containing the incorporated iminoisoindolin-1-one moiety

The copper(ii)-mediated integration between various 3-iminoisoindolin-1- ones and neat organonitriles (which play a dual role of solvent and reactant), under heating for ca. 12 h, and without requiring any base, accomplishes the release of the solid (1,3,5-triazapentadienato)CuII complexes [Cu{HN=C(R)N=C(C6R1R2R3R 4CO)N}2] (1-11) bearing the incorporated iminoisoindolin-1-one fragment. These compounds were isolated in moderate to good yields (44-78%) and do not require further purification. The iminoisoindolinone-nitrile coupling is CuII-mediated and has a general character insofar as it can be efficiently applied for both unsubstituted (R1-R4 = H) and substituted iminoisoindolin-1-ones (R1, R3, R4 = H, R 2 = Me; R1, R4 = H, R2, R 3 = Cl; R1-R4 = F), and a wide range of nitriles (R = Me, Et, Prn, Pri, C6H 11, CH2Ph). Complexes 1-11 were characterized by elemental analyses (C, H, N), FAB+-MS, IR spectroscopy, and additionally compounds 1, 2 and 4 by single-crystal X-ray diffraction. The Royal Society of Chemistry 2008.