108164-63-2Relevant academic research and scientific papers
Studies on catalytic asymmetric Nozaki-Hiyama propargylation
Inoue, Masahiro,Nakada, Masahisa
, p. 2977 - 2980 (2007/10/03)
(Equation Presented) Catalytic asymmetric Nozaki-Hiyama propargylation with ligand 1c proceeds with good to excellent enantioselectivity. Tuning of ligand 1 dramatically changes the enantioselectivity, and we propose models A and B to explain the change a
Lead Promoted Barbier-Type Reaction of Propargyl Bromide with Aldehydes
Tanaka, Hideo,Hamatani, Takeshi,Yamashita, Shiro,Torii, Sigeru
, p. 1461 - 1462 (2007/10/02)
The first example of lead promoted "Barbier-type" (in situ Grignard) reaction has been demonstrated by the reaction of propargyl bromide with aldehydes in a Pb/Bu4NBr/Me3SiCl/DMF system.
