108183-32-0Relevant academic research and scientific papers
Synthesis of α-heterocyclic α-aminophosphonates,1 part II: Morpholine, piperidine, pyrrolidine, tetrahydrofurylmethylamine, N-benzyl-N-methylamine, and aniline derivatives
Boukallaba,Elachqar,El Hallaoui,Alami,El Hajji,Labriti,Atmani,El Bali,Lachkar,Allouchi,Martinez,Rolland
, p. 1045 - 1052 (2007)
α,α-Diaminomethyl phosphonate derivatives were synthesized by N-alkylation of nitrogen heterocycles or primary amines with diethyl α-bromo-α-aminomethyl phosphonate.
Syntheses of unusual 1-aminophosphonic acids via Diels-Alder reactions of diethyl (N-acyliminomethyl)phosphonates
Schrader,Steglich
, p. 1153 - 1156 (2007/10/02)
(N-Acyliminomethyl)phosphonates 3 react with electron-rich dienes in (4 + 2)-cycloadditions either as dienophiles or as diene components to yield 3-(diethoxy)phosphoryl-2-azabicyclo [2.2.1] hept-5-enes 4 and 2-(diethoxy)phosphoryl-2,3-dihydro-4(1H)pyridon
Synthese von 1-Aminophosphonsaeure ueber Acyliminophosphonsaeure-Ester
Schrader, Thomas,Kober, Reiner,Steglich, Wolfgang
, p. 372 - 375 (2007/10/02)
1-Acylaminomethylphosphonates 1 on reaction with N-bromosuccinimide yield 1-acylamino-1-bromomethylphosphonates 2, which on treatment with tertiary amines are converted into acyliminophosphonates 3.The latter react in situ with nucleophiles like enamines,
