108203-70-9Relevant articles and documents
Stability of the zwitterionic liquid butyl-methyl-imidazol-2-ylidene borane
Tr?ger-Müller, Steffen,Antonietti, Markus,Liedel, Clemens
, p. 11437 - 11443 (2018)
Modification of the C2 position of the standard 1-butyl-3-methyl imidazolium cation by a borohydride group leads to a zwitterionic liquid (ZIL). The resulting imidazol-2-ylidene borane ZIL is liquid at room temperature. Dynamic viscosity as well as thermal and electrochemical stability are investigated. Thermal decomposition follows a similar pathway as in comparable imidazolium ionic liquids. The surprisingly low viscosity and good reductive stability make it a promising candidate for electrochemical applications.
Lithium-coordinating ionic conductor for solid-state dye-sensitized solar cells
Li, Juan,Wang, Zhong-Sheng
, p. 56967 - 56973 (2015)
A new solid-state ionic conductor is synthesized by linking an ether group to the nitrogen-atom of 1,2-dimethylimidazole with an iodide counter anion, and the single crystal structure is determined using X-ray crystallographic analysis. Replacement of the
Imidazolium Cations with Exceptional Alkaline Stability: A Systematic Study of Structure-Stability Relationships
Hugar, Kristina M.,Kostalik, Henry A.,Coates, Geoffrey W.
supporting information, p. 8730 - 8737 (2015/07/27)
Highly base-stable cationic moieties are a critical component of anion exchange membranes (AEMs) in alkaline fuel cells (AFCs); however, the commonly employed organic cations have limited alkaline stability. To address this problem, we synthesized and characterized the stability of a series of imidazolium cations in 1, 2, or 5 M KOH/CD3OH at 80 °C, systematically evaluating the impact of substitution on chemical stability. The substituent identity at each position of the imidazolium ring has a dramatic effect on the overall cation stability. We report imidazolium cations that have the highest alkaline stabilities reported to date, >99% cation remaining after 30 days in 5 M KOH/CD3OH at 80 °C.