87373-11-3Relevant academic research and scientific papers
Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters
Ma, Sandy,Reeves, Corey M.,Craig II, Robert A.,Stoltz, Brian M.
, p. 4208 - 4212 (2014/06/09)
The palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters derived from 4-tert-butylcyclohexanone is described. These experiments were performed to elucidate our understanding of stereoablative enantioconvergent catalysis. A
Kinetics of Decarboxylation of the Two Epimers of 5-tert-Butyl-1-methyl-2-oxocyclohexanecarboxylic Acid: Lack of Stereoelectronic Control in β-Keto Acid Decarboxylation
Kayser, Robert H.,Brault, Margaret,Pollack, Ralph M.,Bantia, Shanta,Sadoff, Scott F.
, p. 4497 - 4502 (2007/10/02)
Rates of decarboxylation of the two epimers of 5-tert-butyl-1-methyl-2-oxocyclohexanecarboxylic acid have been measured under both acidic and basic conditions at 25 deg C.The decomposition of isomer 1e (methyl and tert-butyl trans) is more rapid than that
