1082469-76-8

Basic information

• Product Name: methyl (Z)-3-(m-tolylamino)but-2-enoate
• Synonyms: methyl (Z)-3-(m-tolylamino)but-2-enoate
• CAS NO: 1082469-76-8
• Molecular Weight: 205.257
• Mol File: 1082469-76-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl (Z)-3-(m-tolylamino)but-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-3-(m-tolylamino)but-2-enoate(1082469-76-8)
• EPA Substance Registry System: methyl (Z)-3-(m-tolylamino)but-2-enoate(1082469-76-8)

Safety Data

• Hazardous Substances Data: 1082469-76-8(Hazardous Substances Data)

Upstream product

• 105-45-3 acetoacetic acid methyl ester 
• 108-44-1 1-amino-3-methylbenzene 
• 23326-27-4 Methyl 2-butynoate 

Downstream Products

• 1082470-14-1 methyl 2,6-dimethylindole-3-carboxylate 
• 1082470-16-3 methyl 2,4-dimethylindole-3-carboxylate 
• 1393485-81-8 methyl 3-(4-fluorophenyl)-5-methyl-1-(m-tolyl)-1H-pyrazole-4-carboxylate 
• 1259438-05-5 methyl 3-ethyl-5-methyl-1-(3-methylphenyl)-1H-pyrazole-4-carboxylate 

Relevant articles and documents

Ag/CNT-catalyzed hydroamination of activated alkynes with aromatic amines

As a nanoparticle support material, carbon nanotubes (CNTs) provide a certain potential activation of catalysis in heterogeneous catalytic organic reactions. Herein, an efficient Ag/CNT-catalyzed synthesis of enamines via hydroamination of activated alkynes with aromatic amines has been described. This catalyst still retains catalytic activity after being recycled and reused three times. In addition, it represents a green and environmentally friendly process for preparation of enamines. Copyright 2013 John Wiley & Sons, Ltd. Ag/CNTs catalysis has been developed to synthesize enamines via hydroamination of asymmetry alkylnates with aromatic amines. The catalysis can be recycled and reused 3 times, which also remain catalytic activity. In addition, it represents a green and environmentally friendly process for preparation of enamines. Copyright

Palladium-catalyzed oxidative cyclization of N-aryl enamines: From anilines to indoles

(Chemical Equation Presented) The special advantage of the title reaction to form substituted indoles 2 lies within the broad scope of the transformation: A multitude of N-aryl enaminones 1 can be prepared readily in one step from commercially available anilines. Furthermore, anilines can be converted directly in a one-pot process into the indole products. R1 = H, Me, OMe, Cl, F, carbonyl functionality, CN, fused aryl; R2 = alkyl, aryl; R 3 = alkyl, O-alkyl.