1083077-81-9Relevant articles and documents
Conformational, steric and electronic effects on the site- and chemoselectivity of the metal-catalyzed reaction of N-bis(trimethylsilyl)methyl, N-(2-indolyl)methyl α-diazoamides
Zhang, Bao,Wee, Andrew G. H.
, p. 4597 - 4608 (2012/07/28)
The Rh(ii)- and Cu(ii)-catalyzed reactions of N-bis(trimethylsilyl)methyl, N-(2-indolyl)methyl α-diazoamides are investigated to delineate how conformational, steric and electronic factors influence the site- and chemoselectivity of the metallocarbenoid r
Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl) methyl diazoamides: An entry into the β-carboline ring system
Zhang, Bao,Wee, Andrew G. H.
supporting information; experimental part, p. 4837 - 4839 (2009/03/12)
The intramolecular metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(TMS)methyl diazoamides proceeds with high conformational control and chemoselectivity to give cyclopropyl derivatives, which rearrange to β-carboline products. The Royal Society of