108446-93-1Relevant academic research and scientific papers
Imino-λ3-iodane and Catalytic Amount of I2-Mediated Synthesis of N-Allylsulfenamides via [2,3]-Sigmatropic Rearrangement
Makitalo, Cody L.,Mironova, Irina A.,Rohde, Gregory T.,Saito, Akio,Yoshimura, Akira,Yusubov, Mekhman S.,Yusubova, Rosa Y.,Zhdankin, Viktor V.
, p. 6433 - 6439 (2020)
A facile metal-free [2,3]-sigmatropic rearrangement reaction of allyl sulfides via N-sulfilimine intermediates has been developed. Treatment of allyl sulfides with imino-λ3-iodanes in the presence of a catalytic amount of elemental iodine allow
Sigmatropic Rearrangement of Cyclic α-Vinyl Sulfonium Imides: Formation of Thiazocine, Thiazonine, Thiazecine Derivatives
Sashida, Haruki,Tsuchiya, Takashi
, p. 3682 - 3687 (2007/10/02)
Thermolysis of the cyclic α-vinyl sulfonium p-toluenesulfonylimides (6a-c), prepared from 2-vinylthiolane (5a), 2-vinylthiane (5b), and 2-vinylthiepane (5c) by treatment with chloramine T, resulted in -sigmatropic rearrangement with ring-expansion to
THERMAL RING EXPANSION OF 2-VINYLTHIACYCLOALKANE N-IMIDES BY -SIGMATROPIC REARRANGEMENT
Sashida, Haruki,Tsuchiya, Takashi
, p. 1303 - 1306 (2007/10/02)
The thermolysis of the 2-vinylthiacyclo-pentene, -hexane, and -heptane N-(p-toluenesulfonyl)imides (7) resulted in the -sigmatropic rearrangement to give the corresponding ring expansion products (8).
