108474-32-4

Upstream product

• 158918-49-1 N’-(2-bromobenzylidene)-4-methylbenzenesulfonohydrazide 
• 65487-97-0 (S)-(+)-2-methoxy-1-phenylethanol 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 
• 6630-33-7 ortho-bromobenzaldehyde 
• 2039-88-5 2-bromostyrene 
• 36901-75-4 (2-bromobenzyl)triphenylphosphonium bromide 
• 1486-28-8 diphenyl(methyl)phosphine 
• 1377975-13-7 2-bromobenzylmethyldiphenylphosphonium bromide 
• 38274-16-7 2-bromo-1-(trimethylsilylethynyl)benzene 
• 583-55-1 1-Bromo-2-iodobenzene 
• 766-46-1 2-bromo-1-ethynylbenzene 
• 38399-13-2 2,2'-dibromotolane 
• 95-46-5 2-methylphenyl bromide 

Downstream Products

• 13528-44-4 cis-2,3-bis(2-bromophenyl)oxirane 
• 1415246-00-2 5-mesityl-5H-dibenzo[b,f]phosphepine 
• 1591698-54-2 2,7-bis(N,N,-di-(p-tolyl)amino)-5,5,10,10-tetraphenyl-5,10-dihydroindeno[2,1-a]indene 
• 91861-70-0 5,10-dihydro-5,5,10,10-tetraphenyl-indeno[2,1-a]indene 
• 1591698-52-0 2,7-dibromo-5,5,10,10-tetraphenyl-5,10-dihydroindeno[2,1-a]indene 
• 1567990-40-2 C₄₀H₃₂O₂ 
• 31101-69-6 5,5-diphenyl-5H-dibenzo[b,f]silepine 

Relevant academic research and scientific papers

Phenacenes: A family of graphite ribbons. 1. Syntheses of some [7]phenacenes by stilbene-like photocyclizations

The largest previously reported phenacene, the name we propose for the family of polycyclic aromatic compounds having fused benzene rings in an extended phenanthrene-like structural motif, contains only six rings ([6]phenacene). We have employed stilbene-like photocyclizations to synthesize the unsubstituted [7]phenacene, an extremely insoluble compound, as well as 2,13-di-n-pentyl[7]phenacene and 2,13-di-tert-butyl[7]phenacene, two alkyl-substituted derivatives with greatly improved solubilities.

Ruthenium(II) porphyrin catalyzed cyclopropanation of alkenes with tosylhydrazones

The diastereoselective ruthenium(II) porphyrin catalyzed cyclopropanation of a variety of alkenes with aryl diazomethanes generated in situ from stable tosylhydrazone derivatives, was achieved in good to excellent yields (up to 92%) and product turnovers.

Intramolecular biaryl coupling: asymmetric synthesis of the chiral B-ring unit of pradimicinone

The combination of palladium-catalyzed intramolecular biaryl coupling with enantioselective dihydroxylation of achiral stilbenes provides an efficient, two-step route to the chiral 9,10-dihydrophenanthrenediol unit of the pradimicins and benanomicins.

Aluminepin: Aluminum analogues of borepin and gallepin

We report synthesis of dibenzoaluminepin as the first aluminepin, an aluminum analogue of borepin and gallepin. This compound contains one molecule of ethereal solvent on the Al atom, which adopts a tetrahedral geometry. The central 7-membered aluminepin

Modular Approach to the Synthesis of Two-Dimensional Angular Fused Acenes

Herein, we present a modular approach to pristine angularly fused planar acenes. The approach includes the Pd-catalyzed fusion of several building blocks and implements a dehydrative ?-extension (DPEX) reaction as a key step enabling facile access to diverse two-dimensional acenes. The scope was demonstrated on nine examples with up to quantitative yield.

Copper-catalyzed double intramolecular ullmann coupling for the synthesis of diastereomerically and enantiomerically pure 4b,9b-dihydrobenzofuro[3,2-b]benzofurans

The copper-catalyzed double intramolecular Ullmann coupling of syn-1,2-bis(2-bromoaryl)ethane-1,2-diols with catalytic amounts of CuII oxinate as the copper source, K3PO4 as a base, and KI as a reductant in aqueous acetoni

Synthesis of Ring-Locked Tetracyclic Dithienocyclopentapyrans and Dibenzocyclopentapyran via 1,5-Hydride Shift and Copper-Catalyzed C-O Bond Formation for Nonfullerene Acceptors

We discovered a unique synthetic route to construct 2H-pyran-containing tetracyclic dithienocyclopentapyran (DTCP) and dibenzocyclopentapyran (DBCP) architectures. The synthesis involves an acid-induced dehydration cyclization followed by a [1,5] hydride-shift isomerization to form a cyclopentanone moiety which was converted to the pyran-embedded tetracyclic products by a CuI-catalyzed intramolecular C-O bond formation in good yield. DTCP was used as a building block to prepare an acceptor-donor-acceptor (A-D-A) type n-type material DTCP-BC leading to a solar cell efficiency of 9.32%.

E, Z -Selectivity in the reductive cross-coupling of two benzaldehydes to stilbenes under substrate control

Unsymmetrical E- and Z-stilbenes can be synthesized from two differently substituted benzaldehydes in a MesP(TMS)Li-promoted reductive coupling sequence. Depending on the order of addition of the two coupling partners, the same olefin can be produced in either E- or Z-enriched form under identical reaction conditions. A systematic study of the correlation between the stereochemical outcome of the reaction and the substitution pattern at the two aldehydes is presented. The results can be used as guidelines to predict the product stereochemistry. This journal is

Condensed cyclic compound and organic light-emitting device comprising the same

Disclosed are a condensed cyclic compound displayed as chemical formula 1, and an organic light emitting device having the same. The organic light emitting device including the condensed cyclic compound has high brightness, high efficiency, and excellent durability.COPYRIGHT KIPO 2018

Synthesis of a guanidine NHC complex and its application in borylation reactions

Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were isolated and fully characterized. These Cu complexes are found to be versatile catalysts for hydroboration, semihydrogenation and carboboration of alkynes in a highly stereo- and regioselective fashion.