1085182-80-4Relevant academic research and scientific papers
Cu(I)-catalyzed hetero-Diels-Alder reaction between danishefsky-type siloxy dienes and ketones
Chen, I.-Hon,Oisaki, Kounosuke,Kanai, Motomu,Shibasaki, Masakatsu
supporting information; experimental part, p. 5151 - 5154 (2009/06/06)
(Chemical Equation Presented) A general catalytic method for the hetero-Diels - Alder reaction between Danishefsky-type siloxy dienes and ketones was developed. Optimum results were produced with a catalyst generated from CuOTf·(C6H6)1/2 and TBAT with Ph 3PO as the catalytic additive. This reaction was extended to an asymmetric variant, using a Cu(I)-Walphos catalyst.
