108530-14-9Relevant academic research and scientific papers
Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes
Liu, Zhijian,Larock, Richard C.
, p. 13112 - 13113 (2005)
An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N σ-bond addition of amides and S-N σ-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided. Copyright
Interrupted reduction of CF3SO2Cl using tricyclohexylphosphine allows for electrophilic trifluoromethylsulfinylation
Chachignon, Hélène,Cahard, Dominique
, p. 82 - 88 (2017)
The monoreduction of trifluoromethanesulfonyl chloride by an appropriate phosphine, preferentially tricyclohexylphosphine, generates the reactive trifluoromethanesulfinyl chloride CF3SOCl as donor of CF3S(O)+ cation. The direct trifluoromethylsulfinylation of indoles, pyrroles, other azaarenes, amines, and phenols was successfully achieved in moderate to high yields.
A new equivalent of the CF3S(O)+ cation. Synthesis of trifluoromethanesulfinates and trifluoromethanesulfinamides
Billard, Thierry,Greiner, Alfred,Langlois, Bernard R.
, p. 7243 - 7250 (1999)
The solution of sodium trifluoromethanesulfinate (sodium 'triflinate' and phosphoryl chloride (2/1), in AcOEt, behaves like an equivalent of the CF3S(O)+ cation. It can be used in situ to prepare trifluoromethanesulfinates (CF3S(O)OR) or trifluoromethanesulfinamides (CF3S(O)NHR) at room temperature from alcohols or amines, respectively.
Perfluoroalkylation of heterocumulenes with trimethyl(perfluoroalkyl)silanes in the presence of fluoride ions: Synthesis of perfluoroalkanesulfinyl amides from N-organylsulfinyl amines
Yagupolskii, Yurii L.,Kirij, Nataliya V.,Shevchenko, Aleksey V.,Tyrra, Wieland,Naumann, Dieter
, p. 3029 - 3031 (2007/10/03)
Trimethyl(perfluoroalkyl)silanes react in the presence of fluoride ions with N-organylsulfinylamines under mild conditions to give the corresponding perfluoroalkanesulfinyl amides in high yields.
