108675-05-4Relevant academic research and scientific papers
Metal-assisted reactions. Part 29. Structure and hydrogenolysis of C-N bonds in derivatives of aromatic amines. Bond length and electronegativity changes from X-ray crystallographic data
Brigas, Amadeu F.,Clegg, William,Dillon, Christopher J.,Fonseca, Custodia F.C.,Johnstone, Robert A.W.
, p. 1315 - 1324 (2001)
Pseudosaccharyl and phenyltetrazolyl derivatives 1-6 were prepared with the aim of weakening the originally strong C-N bond in aromatic amines and facilitating its hydrogenolysis. Structural analyses of the amines 1-6 by 1H and 13C NMR spectroscopy and X-ray diffraction methods have revealed major changes in C-N bond lengths on derivatization as a result of changes in conjugation. These changes are discussed in relation to the observed reactivity of compounds 1-6 towards catalytic and non-catalytic C-N bond hydrogenolysis.
Synthesis and Spectroscopic Properties of Some New Substituted Saccharin Anils
Salman, Salman R.,Subber, Amjad K.,Hussein, F. A.,Shubber, S. K.
, p. 391 - 393 (2007/10/02)
Fourteen new substituted saccharin anils have been synthesized by the reaction of pseudosaccharin chloride with various substituted anilines.The IR, proton NMR, and carbon-13 NMR spectral properties are presented and discussed.
