108713-90-2

Upstream product

• 13263-74-6 D-xylose diethyl dithioacetal 
• 108713-88-8 5-O-trityl-D-xylose diethyl dithioacetal 
• 100-39-0 benzyl bromide 
• 201603-40-9 (2R,3S,4R)-5-(tert-Butyl-dimethyl-silanyloxy)-1,1-bis-ethylsulfanyl-pentane-2,3,4-triol 
• 201603-52-3 tert-Butyl-dimethyl-((2R,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane 
• 77943-32-9 2,3,4-tri-O-benzyl-β-D-xylopyranose 
• 75-08-1 ethanethiol 
• 18039-26-4 2,3,4-tri-O-benzyl-D-xylopyranose 
• 94898-45-0 C₄₉H₅₂O₄S₂ 

Downstream Products

• 138925-01-6 2-((2R,3S,4R)-2,3,4-Tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyl)-isoindole-1,3-dione 
• 289046-05-5 2,3,4-tri-O-benzyl-5-O-methanesulfonyl-D-xylose diethyl dithioacetal 
• 108713-96-8 2-[(2S,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentyl]-malonic acid dimethyl ester 
• 108713-95-7 2-[(2S,3R,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentylidene]-malonic acid dimethyl ester 
• 125258-11-9 (1R,2R,3R,4S,6R)-2,3,4-Tris-benzyloxy-6-hydroxymethyl-cyclohexanol 
• 108813-43-0 (3R,4R,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-methanol 
• 94898-37-0 methyl (3R,4R,5S)-3,4,5-tris(benzyloxy)-1-cyclohexene-1-carboxylate 
• 108713-97-9 methyl (4S,5R,6R)-4,5,6-tris(benzyloxy)-7-hydroxy-2-(methoxycarbonyl)heptanoate 
• 94898-39-2 (1R,2R,3R,4R,5S)-2-acetoxy-1-(acetoxymethyl)-3,4,5-tris(benzyloxy)cyclohexane 
• 94898-39-2 (1S,2S,3R,4R,5S)-2-acetoxy-1-(acetoxymethyl)-3,4,5-tris(benzyloxy)cyclohexane 
• 108813-40-7 dimethyl (2S,3R,4R,5S)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 108813-41-8 dimethyl (2R,3R,4R,5S)-2-acetoxy-3,4,5-tris(benzyloxy)cyclohexane-1,1-dicarboxylate 
• 108713-94-6 (2R,3S,4R)-2,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentanal 
• 116384-34-0 (2R,3S,4R,5E)-2,3,4-tribenzyloxyocta-5,7-diene-1-al 

Relevant academic research and scientific papers

A facile synthesis of 1-thiopentofuranoside

β-1-Thio-2,3,5-tribenzylarabinofuranoside and α-1-thio-2,3,5- tribenzylxylopyranoside were easily prepared using ethanethiol or benzenethiol in the presence of conc. hydrochloric acid at room temperature, while a dithioacetal was obtained from the corresp

Free Radical Studies and Solutions to the Synthesis of (+)-Cyclophellitol

D-Xylose serves as a starting material for approaches to the synthesis of the glucosidase inhibitors, (+)-cyclophellitol (1) and (+)-epi-cyclophellitol (2). An investigation of the cyclization of diastereomeric oxiranyl radicals to achieve this goal was m

INTRAMOLECULAR REACTIONS OF COMPOUNDS DERIVED FROM SUGARS. PART II. STEREOCONTROLLED INTRAMOLECULAR DIELS-ALDER CYCLIZATIONS OF 1,6(E,Z),8-NONATRIENES AND 1-AZA-6(E,Z),8-NONANTRIENES

Intramolecular Diels-Alder reactions of E,Z mixtures of nonatrienes 6 and 9 led to the exclusive formation of the bicyclic compounds 10 and 11 respectively.

COMPLETE STEREOSELECTIVITY IN THE INTRAMOLECULAR DIELS-ALDER REACTION OF A TRIENE DERIVATIVE FROM D-XYLOSE

Thermal intramolecular Diels-Alder reaction of triene 6 yielded the bicyclic derivative 7 with excellent stereoselectivity.

A Novel Transformation of Four Aldoses to Some Optically Pure Pseudohexopyranoses and a Pseudopentofuranose, Carboxylic Analogues of Hexopyranoses and Pentofuranose. Synthesis of Derivatives of (1S,2S,3R,4S,5S)-, (1S,2S,3R,4R,5S)-, (1R,2R,3R,4R,5S)-, (1S,

Knoevenagel reactions with dimethyl malonate of the suitably protected acylic aldehydes 6, 20, 34, and 46, which were prepared from D-ribose, D-xylose, D-arabinose, and D-erythrose, respectively, proceeded smoothly to provide α,β-unsaturated diesters 7, 2