1089665-81-5

Basic information

• Product Name: 2-benzyl-2-(2-nitro-1-phenylethyl)ethanal
• Synonyms: 2-benzyl-2-(2-nitro-1-phenylethyl)ethanal
• CAS NO: 1089665-81-5
• Molecular Weight: 283.327
• Mol File: 1089665-81-5.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: 2-benzyl-2-(2-nitro-1-phenylethyl)ethanal(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzyl-2-(2-nitro-1-phenylethyl)ethanal(1089665-81-5)
• EPA Substance Registry System: 2-benzyl-2-(2-nitro-1-phenylethyl)ethanal(1089665-81-5)

Safety Data

• Hazardous Substances Data: 1089665-81-5(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 5153-67-3 nitrostyrene 
• 102-96-5 (2-nitroethenyl)benzene 
• 104-55-2 3-phenyl-propenal 
• 15241-23-3 (Z)-nitrostyrene 
• 1310420-09-7 (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}-1-[(1S,2S,3S,4R)-2-nitro-3-phenyl-4-(propan-2-yl)cyclobutyl]pyrrolidine 
• 75-52-5 nitromethane 
• 100-52-7 benzaldehyde 

Downstream Products

• 1301224-82-7 (2S,3R,4S,5R)-ethyl-5-benzyl-6-hydroxy-3-nitro-4-phenyltetrahydro-2H-pyran-2-carboxylate 

Relevant articles and documents

Amphiphilic immobilized diphenylprolinol alkyl ether catalyst on PS-PEG resin

Diphenylprolinol silyl ether is a widely used organocatalyst, and its immobilization on a solid support was investigated for the easy recycling and reuse of this catalyst. Because a silyl ether bond of the catalyst is weak, its alkyl ether was attached to polymers such as a polyquinoxaline-based polymer, a polystyrene polymer (PS) resin, and a polystyrenepoly(ethylene glycol) graft copolymer (PS-PEG) resin. Although a polymer-supported organocatalyst generally decreases its reactivity compared with the monomer catalyst, diphenylprolinol anthrylmethyl ether supported on PS-PEG was found to be a reactive organocatalyst; it catalyzed the Michael reaction of an aldehyde and a nitroalkene in water without an organic solvent being present, with excellent diastereo- and enantioselectivities.

Conformational Control of Tetrahydropyran-Based Hybrid Dipeptide Catalysts Improves Activity and Stereoselectivity

Herein, we introduce and demonstrate how carbohydrates can be used as conformational control units of organocatalysts to tune their catalytic properties. New hybrid dipeptide-like organocatalysts based on ζ-sugar aminoacids and proline were prepared and t

D -Prolyl-2-(trifluoromethylsulfonamidopropyl)pyrrolidine: An Organocatalyst for Asymmetric Michael Addition of Aldehydes to β-Nitroalkenes at Ambient Conditions

Four 2-(trifluoromethylsulfonamidoalkyl)pyrrolidines and their d-prolinamides were prepared and screened as organocatalysts for the Michael addition reaction of aldehydes with β-nitroalkenes at rt and without the use of additives. d-Prolyl-2-(trifluoromet