109200-97-7

Upstream product

• 109200-97-7 (1S,2R,4S,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2S,4S,4aR,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 87669-36-1 2-phenyl-3-phenyl-2-thioxo-2-phosphabicyclo<4.4.0>decan-5-one 
• 109200-97-7 (1S,2R,4R,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2S,4R,4aR,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 87669-36-1 (1S,2S,4aS,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 87669-36-1 (1S,2S,4aR,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 87669-36-1 (1S,2R,4aS,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 

Downstream Products

• 109200-97-7 (1S,2S,4S,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2S,4R,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-99-9 Acetic acid (1S,2R,4S,4aS,8aR)-1,2-diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-yl ester 

Relevant academic research and scientific papers

UNUSUAL REDUCTION OF HETEROCYCLIC KETONES

Phosphorinanone and phosphabicyclodecanone derivatives containing four-coordinate phosphorus are reduced to secondary alcohols when heated with alcohols or glycols in the presence of alkali-metal hydroxides.

ISOMERIZATION OF C-FUNCTIONAL 2-PHOSPHABICYCLODECANE 2-SULFIDE DERIVATIVES

The electron-acceptor thiophosphoryl group in 5-oxo and 5-hydroxy derivatives of 2-phenyl-3-R-2-phosphabicyclodecane 2-sulfides is responsible for the mobility of hydrogen atoms on neighboring carbon atoms.Under the conditions of basic catalysis is