87669-36-1

Upstream product

• 87669-36-1 (1S,2S,4aR,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 87669-36-1 (1S,2S,4aS,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 87669-36-1 (1S,2R,4aS,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 

Downstream Products

• 109200-97-7 (1S,2S,4S,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2S,4R,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2R,4S,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2R,4R,4aR,8aS)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2S,4S,4aS,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 87669-36-1 2-phenyl-3-phenyl-2-thioxo-2-phosphabicyclo<4.4.0>decan-5-one 
• 87669-36-1 (1S,2S,4aR,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 87669-36-1 (1S,2R,4aS,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 109200-97-7 (1S,2S,4S,4aR,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2S,4R,4aR,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 87669-36-1 (1S,2S,4aS,8aR)-1,2-Diphenyl-1-thioxo-octahydro-1λ⁵-phosphinolin-4-one 
• 109200-97-7 (1S,2R,4S,4aS,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-97-7 (1S,2R,4R,4aS,8aR)-1,2-Diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-ol 
• 109200-99-9 Acetic acid (1S,2R,4R,4aS,8aR)-1,2-diphenyl-1-thioxo-decahydro-1λ⁵-phosphinolin-4-yl ester 

Relevant academic research and scientific papers

EQUILIBRIA OF 2,5-DIMETHYL-1-PHENYL-1-THIOXO-4-PHOPHORINANONE STEREOISOMERS. CONFORMATIONAL ENERGIES OF THE SUBSTITUENTS IN PHOSPHORUS-CONTAINING HETEROCYCLES

The most preferable stereoisomers in series of vicinally substituted P-phenyl-4-phosphorinanones and phosphabicyclodecan-5-ones are those with an equatorial orientation of the phenyl group attached to the phosphorus atom.The conformational free energies of the methyl and phenyl substituents in these compounds are greater than in cyclohexane derivatives.

ISOMERIZATION OF C-FUNCTIONAL 2-PHOSPHABICYCLODECANE 2-SULFIDE DERIVATIVES

The electron-acceptor thiophosphoryl group in 5-oxo and 5-hydroxy derivatives of 2-phenyl-3-R-2-phosphabicyclodecane 2-sulfides is responsible for the mobility of hydrogen atoms on neighboring carbon atoms.Under the conditions of basic catalysis is