109240-01-9Relevant academic research and scientific papers
Sulfinylnitriles: Sulfinyl-metal exchange-alkylation strategies
Nath, Dinesh,Fleming, Fraser F.
supporting information, p. 2023 - 2029 (2013/03/14)
Adding organolithiums, Grignard reagents, or zincates to sulfinylnitriles triggers a facile sulfinyl-metal exchange to afford N- or C-metalated nitriles. Sulfinyl-magnesium exchange-alkylations efficiently install quaternary and tertiary centers, even in
DIENOPHILIE DES OLEFINES CAPTODATIVES: CYCLOADDITIONS DE DIELS-ALDER DE L'α-METHYLTHIO-ACRYLONITRILE ET TRANSFORMATION DES ADDUITS
Boucher, Jean-Luc,Stella, Lucien
, p. 3871 - 3886 (2007/10/02)
The cycloaddition reactions of the α-methylthio-acrylonitrile with 1,3-dienes are investigated.The uncatalyzed thermal reactions proceed in high yields very stereoselectively with cyclic dienes and especially even room temperature with cyclopentadiene.In
