109262-85-3Relevant articles and documents
BASE-ASSISTED MIGRATION OF TRIMETHYLSILYL GROUP FROM CARBON TO OXYGEN IN γ-TRIMETHYLSILYL-γ,δ-UNSATURATED ALCOHOLS, γ-TRIMETHYLSILYL-γ,δ-EPOXY ALCOHOLS, AND β-TRIMETHYLSILYL-β,γ-EPOXY ALCOHOLS TO THE CORRESPONDING SILYL ETHERS
Kobayashi, Yuichi,Uchiyama, Hiroshi,Kanbara, Hiroshi,Kusakabe, Masato,Sato, Fumie
, p. 549 - 561 (2007/10/02)
Treatment of γ-trimethylsilyl-γ,δ-unsaturated alcohols 2, γ-trimethylsilyl-γ,δ-epoxy alcohols 3-6, and β-trimethylsilyl-β,γ-epoxy alcohols 9-12 with NaH in HMPA or t-BuOK in THF brought about facile migration of SiMe3 group from carbon to oxygen to produc