82849-04-5

Upstream product

• 77302-12-6 (2R,3S)-5-Benzyloxy-3-hydroxy-2-methyl-pentanoic acid 
• 109262-88-6 ((2R,3S)-5-Benzyloxy-3-methoxymethoxy-2-methyl-1-methylene-pentyl)-trimethyl-silane 
• 109262-85-3 (3S,4R)-1-Benzyloxy-4-methyl-5-trimethylsilanyl-hex-5-en-3-ol 
• 109289-45-4 (3S,4R)-3-Methoxymethoxy-4-methyl-5-trimethylsilanyl-hex-5-enal 
• 109262-87-5 (3S,4R)-3-Methoxymethoxy-4-methyl-5-trimethylsilanyl-hex-5-en-1-ol 
• 109262-86-4 (3S,4S)-1-(benzyloxy)-4-methylhex-5-en-3-ol 
• 100-39-0 benzyl bromide 
• 109262-89-7 ((3S,4S)-3-Methoxy-4-methyl-hex-5-enyloxymethyl)-benzene 
• 82849-03-4 (2S,3S)-5-Benzyloxy-3-methoxy-2-methyl-pentan-1-ol 

Relevant academic research and scientific papers

BASE-ASSISTED MIGRATION OF TRIMETHYLSILYL GROUP FROM CARBON TO OXYGEN IN γ-TRIMETHYLSILYL-γ,δ-UNSATURATED ALCOHOLS, γ-TRIMETHYLSILYL-γ,δ-EPOXY ALCOHOLS, AND β-TRIMETHYLSILYL-β,γ-EPOXY ALCOHOLS TO THE CORRESPONDING SILYL ETHERS

Treatment of γ-trimethylsilyl-γ,δ-unsaturated alcohols 2, γ-trimethylsilyl-γ,δ-epoxy alcohols 3-6, and β-trimethylsilyl-β,γ-epoxy alcohols 9-12 with NaH in HMPA or t-BuOK in THF brought about facile migration of SiMe3 group from carbon to oxygen to produc