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1092837-05-2

Ru(C.ident.CSi(i)Pr3)(PPh3)2Cp is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1092837-05-2 Structure

  • Basic information

    1. Product Name: Ru(C.ident.CSi(i)Pr3)(PPh3)2Cp
    2. Synonyms:
    3. CAS NO:1092837-05-2
    4. Molecular Formula:
    5. Molecular Weight: 872.12
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1092837-05-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Ru(C.ident.CSi(i)Pr3)(PPh3)2Cp(CAS DataBase Reference)
    10. NIST Chemistry Reference: Ru(C.ident.CSi(i)Pr3)(PPh3)2Cp(1092837-05-2)
    11. EPA Substance Registry System: Ru(C.ident.CSi(i)Pr3)(PPh3)2Cp(1092837-05-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1092837-05-2(Hazardous Substances Data)

1092837-05-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1092837-05-2 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,9,2,8,3 and 7 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 1092837-05:
(9*1)+(8*0)+(7*9)+(6*2)+(5*8)+(4*3)+(3*7)+(2*0)+(1*5)=162
162 % 10 = 2
So 1092837-05-2 is a valid CAS Registry Number.

1092837-05-2Downstream Products

1092837-05-2Relevant articles and documents

Reactions of cyano(alkynyl)ethenes with some alkynyl- and diynyl-ruthenium complexes

Armitt, David J.,Bruce, Michael I.,Skelton, Brian W.,White, Allan H.

, p. 3571 - 3581 (2008)

Reactions of Ru(C{triple bond, long}CPh)(PPh3)2Cp with (NC)2C{double bond, long}CR1R2 (R1 = H, R2 = C{triple bond, long}CSiPri3 8; R1 = R2 = C{triple bond, long}CPh 9) have given η3-butadienyl complexes Ru{η3-C[{double bond, long}C(CN)2]CPh{double bond, long}CR1R2}(PPh3)Cp (11, 12), respectively, by formal [2 + 2]-cycloaddition of the alkynyl and alkene, followed by ring-opening of the resulting cyclobutenyl (not detected) and displacement of a PPh3 ligand. Deprotection (tbaf) of 11 and subsequent reactions with RuCl(dppe)Cp and AuCl(PPh3) afforded binuclear derivatives Ru{η3-C[{double bond, long}C(CN)2]CPh{double bond, long}CHC{triple bond, long}C[MLn]}(PPh3)Cp [MLn = Ru(dppe)Cp 19, Au(PPh3) 20]. Reactions between 8 and Ru(C{triple bond, long}CC{triple bond, long}CR)(PP)Cp [PP = (PPh3)2, R = Ph, SiMe3, SiPri3; PP = dppe, R = Ph] gave η1-dienynyl complexes Ru{C{triple bond, long}CC[{double bond, long}C(CN)2]CR{double bond, long}CH[C{triple bond, long}C(SiPri3)]}(PP)Cp (15-18), respectively, in reactions not involving phosphine ligand displacement. The phthalodinitrile C6H(C{triple bond, long}CSiMe3)(CN)2(NH2)(SiMe3) 10 was obtained serendipitously from (Me3SiC{triple bond, long}C)2CO and CH2(CN)2, as shown by an XRD structure determination. The XRD structures of precursor 7 and adducts 11, 12 and 17 are also reported.

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