109459-30-5Relevant academic research and scientific papers
Cyclic vinylogous triflate hemiacetals as new surrogates for alkynyl aldehydes
Kamijo, Shin,Dudley, Gregory B.
, p. 5629 - 5632 (2006)
Cyclic vinylogous triflate hemiacetals can serve as 'synthetic equivalents' for alkynyl aldehydes: treatment of a vinylogous triflate hemiacetal with excess amounts of Grignard reagents produces acyclic alkynyl alcohols in good to high yields. This transf
STUDIES ON THE REDUCTION OF CYCLIC 1,3-DIKETONES VIA THEIR TRIFLATES
Martinez, A. Garcia,Alvarez, R. Martinez,Casado, M. Madueno,Subramanian, L. R.,Hanack, M.
, p. 275 - 280 (2007/10/02)
Using 1,3-Cyclohexadione (1) and 5,5-dimethyl-1,3-Cyclohexadione (11) as examples, it is shown that 1,3-diketones can be transformed into monoketones, monoalcohols, alkanes and unsaturated ketones.
