Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester

Base Information

Chemical Name:Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester
CAS No.:109459-30-5
Molecular Formula:C7H9F3O4S
Molecular Weight:246.207
Hs Code.:
DSSTox Substance ID:DTXSID20548590
Nikkaji Number:J2.341.388D
Mol file:109459-30-5.mol

Synonyms:109459-30-5;Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester;DTXSID20548590;ALUPQGZHKDQMBJ-UHFFFAOYSA-N;3-Hydroxycyclohex-1-en-1-yl trifluoromethanesulfonate

Suppliers and Price of Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:2
Exact Mass:246.01736442
Heavy Atom Count:15
Complexity:351

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC(C=C(C1)OS(=O)(=O)C(F)(F)F)O

Technology Process of Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester

There total 2 articles about Methanesulfonic acid, trifluoro-, 3-hydroxy-1-cyclohexen-1-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 109459-28-1
3-(trifluoromethanesulfonyloxy)-2-cyclohexen-1-one

: 109459-30-5
3-hydroxycyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; n-heptane; at -78 - 20 ℃;
DOI:10.1016/j.tetlet.2006.06.040

Reference yield:

: 504-02-9
1,3-cylohexanedione

: 109459-30-5
3-hydroxycyclohex-1-en-1-yl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) sodium hydride / 1.) dimethoxyethane, room temperature, 25 min, 2.) 2 h, -78 deg C

2: 62 percent / sodium borohydride / methanol / 1 h / 0 °C

With sodium tetrahydroborate; sodium hydride; In methanol;
DOI:10.1016/S0040-4020(01)89955-5